ecearth3/sources/nemo-3.6/NEMO/TOP_SRC/PISCES/P4Z/p4zche.F90

MODULE p4zche
   !!======================================================================
   !!                         ***  MODULE p4zche  ***
   !! TOP :   PISCES Sea water chemistry computed following OCMIP protocol
   !!======================================================================
   !! History :   OPA  !  1988     (E. Maier-Reimer)  Original code
   !!              -   !  1998     (O. Aumont)  addition
   !!              -   !  1999     (C. Le Quere)  modification
   !!   NEMO      1.0  !  2004     (O. Aumont)  modification
   !!              -   !  2006     (R. Gangsto)  modification
   !!             2.0  !  2007-12  (C. Ethe, G. Madec)  F90
   !!                  !  2011-02  (J. Simeon, J.Orr ) update O2 solubility constants
   !!             3.6  !  2016-03  (O. Aumont) Change chemistry to MOCSY standards
   !!----------------------------------------------------------------------
#if defined key_pisces
   !!----------------------------------------------------------------------
   !!   'key_pisces*'                                      PISCES bio-model
   !!----------------------------------------------------------------------
   !!   p4z_che      :  Sea water chemistry computed following OCMIP protocol
   !!----------------------------------------------------------------------
   USE oce_trc       !  shared variables between ocean and passive tracers
   USE trc           !  passive tracers common variables
   USE sms_pisces    !  PISCES Source Minus Sink variables
   USE lib_mpp       !  MPP library
   USE eosbn2, ONLY : nn_eos

   IMPLICIT NONE
   PRIVATE

   PUBLIC   p4z_che          !
   PUBLIC   p4z_che_alloc    !
   PUBLIC   p4z_che_ahini    !
   PUBLIC   p4z_che_solve_hi !

   REAL(wp), PUBLIC, ALLOCATABLE, SAVE, DIMENSION(:,:,:)   :: sio3eq   ! chemistry of Si
   REAL(wp), PUBLIC, ALLOCATABLE, SAVE, DIMENSION(:,:,:)   :: fekeq    ! chemistry of Fe
   REAL(wp), PUBLIC, ALLOCATABLE, SAVE, DIMENSION(:,:,:)   :: chemc    ! Solubilities of O2 and CO2
   REAL(wp), PUBLIC, ALLOCATABLE, SAVE, DIMENSION(:,:,:)   :: chemo2    ! Solubilities of O2 and CO2
   REAL(wp), PUBLIC, ALLOCATABLE, SAVE, DIMENSION(:,:,:,:) :: fesol    ! solubility of Fe
   REAL(wp), PUBLIC, ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   tempis   ! In situ temperature
   REAL(wp), PUBLIC, ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   salinprac  ! Practical salinity

   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   akb3       !: ???
   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   akw3       !: ???
   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   akf3       !: ???
   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   aks3       !: ???
   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   ak1p3      !: ???
   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   ak2p3      !: ???
   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   ak3p3      !: ???
   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   aksi3      !: ???
   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   borat      !: ???
   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   fluorid    !: ???
   REAL(wp), ALLOCATABLE, SAVE, DIMENSION(:,:,:) ::   sulfat     !: ???

   !!* Variable for chemistry of the CO2 cycle

   REAL(wp), PUBLIC ::   atcox  = 0.20946         ! units atm

   REAL(wp) ::   o2atm  = 1. / ( 1000. * 0.20946 )  

   REAL(wp) ::   rgas   = 83.14472      ! universal gas constants
   REAL(wp) ::   oxyco  = 1. / 22.4144  ! converts from liters of an ideal gas to moles

   !                                    ! coeff. for seawater pressure correction : millero 95
   !                                    ! AGRIF doesn't like the DATA instruction
   REAL(wp) :: devk10  = -25.5
   REAL(wp) :: devk11  = -15.82
   REAL(wp) :: devk12  = -29.48
   REAL(wp) :: devk13  = -20.02
   REAL(wp) :: devk14  = -18.03
   REAL(wp) :: devk15  = -9.78
   REAL(wp) :: devk16  = -48.76
   REAL(wp) :: devk17  = -14.51
   REAL(wp) :: devk18  = -23.12
   REAL(wp) :: devk19  = -26.57
   REAL(wp) :: devk110  = -29.48
   !
   REAL(wp) :: devk20  = 0.1271
   REAL(wp) :: devk21  = -0.0219
   REAL(wp) :: devk22  = 0.1622
   REAL(wp) :: devk23  = 0.1119
   REAL(wp) :: devk24  = 0.0466
   REAL(wp) :: devk25  = -0.0090
   REAL(wp) :: devk26  = 0.5304
   REAL(wp) :: devk27  = 0.1211
   REAL(wp) :: devk28  = 0.1758
   REAL(wp) :: devk29  = 0.2020
   REAL(wp) :: devk210  = 0.1622
   !
   REAL(wp) :: devk30  = 0.
   REAL(wp) :: devk31  = 0.
   REAL(wp) :: devk32  = 2.608E-3
   REAL(wp) :: devk33  = -1.409e-3
   REAL(wp) :: devk34  = 0.316e-3
   REAL(wp) :: devk35  = -0.942e-3
   REAL(wp) :: devk36  = 0.
   REAL(wp) :: devk37  = -0.321e-3
   REAL(wp) :: devk38  = -2.647e-3
   REAL(wp) :: devk39  = -3.042e-3
   REAL(wp) :: devk310  = -2.6080e-3
   !
   REAL(wp) :: devk40  = -3.08E-3
   REAL(wp) :: devk41  = 1.13E-3
   REAL(wp) :: devk42  = -2.84E-3
   REAL(wp) :: devk43  = -5.13E-3
   REAL(wp) :: devk44  = -4.53e-3
   REAL(wp) :: devk45  = -3.91e-3
   REAL(wp) :: devk46  = -11.76e-3
   REAL(wp) :: devk47  = -2.67e-3
   REAL(wp) :: devk48  = -5.15e-3
   REAL(wp) :: devk49  = -4.08e-3
   REAL(wp) :: devk410  = -2.84e-3
   !
   REAL(wp) :: devk50  = 0.0877E-3
   REAL(wp) :: devk51  = -0.1475E-3     
   REAL(wp) :: devk52  = 0.
   REAL(wp) :: devk53  = 0.0794E-3      
   REAL(wp) :: devk54  = 0.09e-3
   REAL(wp) :: devk55  = 0.054e-3
   REAL(wp) :: devk56  = 0.3692E-3
   REAL(wp) :: devk57  = 0.0427e-3
   REAL(wp) :: devk58  = 0.09e-3
   REAL(wp) :: devk59  = 0.0714e-3
   REAL(wp) :: devk510  = 0.0
   !
   ! General parameters
   REAL(wp), PARAMETER :: pp_rdel_ah_target = 1.E-4_wp
   REAL(wp), PARAMETER :: pp_ln10 = 2.302585092994045684018_wp

   ! Maximum number of iterations for each method
   INTEGER, PARAMETER :: jp_maxniter_atgen    = 20

   ! Bookkeeping variables for each method
   ! - SOLVE_AT_GENERAL
   INTEGER :: niter_atgen    = jp_maxniter_atgen

   !!* Substitution
#include "top_substitute.h90"
   !!----------------------------------------------------------------------
   !! NEMO/TOP 3.3 , NEMO Consortium (2010)
   !! $Id: p4zche.F90 3977 2017-02-20 14:03:23Z ufla $ 
   !! Software governed by the CeCILL licence     (NEMOGCM/NEMO_CeCILL.txt)
   !!----------------------------------------------------------------------
CONTAINS

   SUBROUTINE p4z_che
      !!---------------------------------------------------------------------
      !!                     ***  ROUTINE p4z_che  ***
      !!
      !! ** Purpose :   Sea water chemistry computed following OCMIP protocol
      !!
      !! ** Method  : - ...
      !!---------------------------------------------------------------------
      INTEGER  ::   ji, jj, jk
      REAL(wp) ::   ztkel, ztkel1, zt , zsal  , zsal2 , zbuf1 , zbuf2
      REAL(wp) ::   ztgg , ztgg2, ztgg3 , ztgg4 , ztgg5
      REAL(wp) ::   zpres, ztc  , zcl   , zcpexp, zoxy  , zcpexp2
      REAL(wp) ::   zsqrt, ztr  , zlogt , zcek1, zc1, zplat
      REAL(wp) ::   zis  , zis2 , zsal15, zisqrt, za1, za2
      REAL(wp) ::   zckb , zck1 , zck2  , zckw  , zak1 , zak2  , zakb , zaksp0, zakw
      REAL(wp) ::   zck1p, zck2p, zck3p, zcksi, zak1p, zak2p, zak3p, zaksi
      REAL(wp) ::   zst  , zft  , zcks  , zckf  , zaksp1
      REAL(wp) ::   total2free, free2SWS, total2SWS, SWS2total

      !!---------------------------------------------------------------------
      !
      IF( nn_timing == 1 )  CALL timing_start('p4z_che')
      !
      ! Computation of chemical constants require practical salinity
      ! Thus, when TEOS08 is used, absolute salinity is converted to 
      ! practical salinity
      ! -------------------------------------------------------------
      IF (nn_eos == -1) THEN
         salinprac(:,:,:) = tsn(:,:,:,jp_sal) * 35.0 / 35.16504
      ELSE
         salinprac(:,:,:) = tsn(:,:,:,jp_sal)
      ENDIF

      !
      ! Computations of chemical constants require in situ temperature
      ! Here a quite simple formulation is used to convert 
      ! potential temperature to in situ temperature. The errors is less than 
      ! 0.04°C relative to an exact computation
      ! ---------------------------------------------------------------------
      DO jk = 1, jpk
         DO jj = 1, jpj
            DO ji = 1, jpi
               zpres = fsdept(ji,jj,jk) / 1000.
               za1 = 0.04 * ( 1.0 + 0.185 * tsn(ji,jj,jk,jp_tem) + 0.035 * (salinprac(ji,jj,jk) - 35.0) )
               za2 = 0.0075 * ( 1.0 - tsn(ji,jj,jk,jp_tem) / 30.0 )
               tempis(ji,jj,jk) = tsn(ji,jj,jk,jp_tem) - za1 * zpres + za2 * zpres**2
            END DO
         END DO
      END DO
      !
      ! CHEMICAL CONSTANTS - SURFACE LAYER
      ! ----------------------------------
!CDIR NOVERRCHK
      DO jj = 1, jpj
!CDIR NOVERRCHK
         DO ji = 1, jpi
            !                             ! SET ABSOLUTE TEMPERATURE
            ztkel = tempis(ji,jj,1) + 273.15
            zt    = ztkel * 0.01
            zsal  = salinprac(ji,jj,1) + ( 1.- tmask(ji,jj,1) ) * 35.
            !                             ! LN(K0) OF SOLUBILITY OF CO2 (EQ. 12, WEISS, 1980)
            !                             !     AND FOR THE ATMOSPHERE FOR NON IDEAL GAS
            zcek1 = 9345.17/ztkel - 60.2409 + 23.3585 * LOG(zt) + zsal*(0.023517 - 0.00023656*ztkel    &
            &       + 0.0047036e-4*ztkel**2)
            chemc(ji,jj,1) = EXP( zcek1 ) * 1E-6 * rhop(ji,jj,1) / 1000. ! mol/(L atm)
            chemc(ji,jj,2) = -1636.75 + 12.0408*ztkel - 0.0327957*ztkel**2 + 0.0000316528*ztkel**3
            chemc(ji,jj,3) = 57.7 - 0.118*ztkel
            !
         END DO
      END DO

      ! OXYGEN SOLUBILITY - DEEP OCEAN
      ! -------------------------------
!CDIR NOVERRCHK
      DO jk = 1, jpk
!CDIR NOVERRCHK
         DO jj = 1, jpj
!CDIR NOVERRCHK
            DO ji = 1, jpi
              ztkel = tempis(ji,jj,jk) + 273.15
              zsal  = salinprac(ji,jj,jk) + ( 1.- tmask(ji,jj,jk) ) * 35.
              zsal2 = zsal * zsal
              ztgg  = LOG( ( 298.15 - tempis(ji,jj,jk) ) / ztkel )  ! Set the GORDON & GARCIA scaled temperature
              ztgg2 = ztgg  * ztgg
              ztgg3 = ztgg2 * ztgg
              ztgg4 = ztgg3 * ztgg
              ztgg5 = ztgg4 * ztgg

              zoxy  = 2.00856 + 3.22400 * ztgg + 3.99063 * ztgg2 + 4.80299 * ztgg3    &
              &       + 9.78188e-1 * ztgg4 + 1.71069 * ztgg5 + zsal * ( -6.24097e-3   &
              &       - 6.93498e-3 * ztgg - 6.90358e-3 * ztgg2 - 4.29155e-3 * ztgg3 )   &
              &       - 3.11680e-7 * zsal2
              chemo2(ji,jj,jk) = ( EXP( zoxy ) * o2atm ) * oxyco * atcox     ! mol/(L atm)
            END DO
          END DO
        END DO



      ! CHEMICAL CONSTANTS - DEEP OCEAN
      ! -------------------------------
!CDIR NOVERRCHK
      DO jk = 1, jpk
!CDIR NOVERRCHK
         DO jj = 1, jpj
!CDIR NOVERRCHK
            DO ji = 1, jpi

               ! SET PRESSION ACCORDING TO SAUNDER (1980)
               zplat   = SIN ( ABS(gphit(ji,jj)*3.141592654/180.) )
               zc1 = 5.92E-3 + zplat**2 * 5.25E-3
               zpres = ((1-zc1)-SQRT(((1-zc1)**2)-(8.84E-6*fsdept(ji,jj,jk)))) / 4.42E-6
               zpres = zpres / 10.0

               ! SET ABSOLUTE TEMPERATURE
               ztkel   = tempis(ji,jj,jk) + 273.15
               zsal    = salinprac(ji,jj,jk) + ( 1.-tmask(ji,jj,jk) ) * 35.
               zsqrt  = SQRT( zsal )
               zsal15  = zsqrt * zsal
               zlogt  = LOG( ztkel )
               ztr    = 1. / ztkel
               zis    = 19.924 * zsal / ( 1000.- 1.005 * zsal )
               zis2   = zis * zis
               zisqrt = SQRT( zis )
               ztc     = tempis(ji,jj,jk) + ( 1.- tmask(ji,jj,jk) ) * 20.

               ! CHLORINITY (WOOSTER ET AL., 1969)
               zcl     = zsal / 1.80655

               ! TOTAL SULFATE CONCENTR. [MOLES/kg soln]
               zst     = 0.14 * zcl /96.062

               ! TOTAL FLUORIDE CONCENTR. [MOLES/kg soln]
               zft     = 0.000067 * zcl /18.9984

               ! DISSOCIATION CONSTANT FOR SULFATES on free H scale (Dickson 1990)
               zcks    = EXP(-4276.1 * ztr + 141.328 - 23.093 * zlogt         &
               &         + (-13856. * ztr + 324.57 - 47.986 * zlogt) * zisqrt &
               &         + (35474. * ztr - 771.54 + 114.723 * zlogt) * zis    &
               &         - 2698. * ztr * zis**1.5 + 1776.* ztr * zis2         &
               &         + LOG(1.0 - 0.001005 * zsal))

               ! DISSOCIATION CONSTANT FOR FLUORIDES on free H scale (Dickson and Riley 79)
               zckf    = EXP( 1590.2*ztr - 12.641 + 1.525*zisqrt   &
               &         + LOG(1.0d0 - 0.001005d0*zsal)            &
               &         + LOG(1.0d0 + zst/zcks))

               ! DISSOCIATION CONSTANT FOR CARBONATE AND BORATE
               zckb=  (-8966.90 - 2890.53*zsqrt - 77.942*zsal        &
               &      + 1.728*zsal15 - 0.0996*zsal*zsal)*ztr         &
               &      + (148.0248 + 137.1942*zsqrt + 1.62142*zsal)   &
               &      + (-24.4344 - 25.085*zsqrt - 0.2474*zsal)      & 
               &      * zlogt + 0.053105*zsqrt*ztkel

               ! DISSOCIATION COEFFICIENT FOR CARBONATE ACCORDING TO 
               ! MEHRBACH (1973) REFIT BY MILLERO (1995), seawater scale
               zck1    = -1.0*(3633.86*ztr - 61.2172 + 9.6777*zlogt  &
                  - 0.011555*zsal + 0.0001152*zsal*zsal)
               zck2    = -1.0*(471.78*ztr + 25.9290 - 3.16967*zlogt      &
                  - 0.01781*zsal + 0.0001122*zsal*zsal)

               ! PKW (H2O) (MILLERO, 1995) from composite data
               zckw    = -13847.26 * ztr + 148.9652 - 23.6521 * zlogt + ( 118.67 * ztr    &
                         - 5.977 + 1.0495 * zlogt ) * zsqrt - 0.01615 * zsal

               ! CONSTANTS FOR PHOSPHATE (MILLERO, 1995)
              zck1p    = -4576.752*ztr + 115.540 - 18.453*zlogt   &
              &          + (-106.736*ztr + 0.69171) * zsqrt       &
              &          + (-0.65643*ztr - 0.01844) * zsal

              zck2p    = -8814.715*ztr + 172.1033 - 27.927*zlogt  &
              &          + (-160.340*ztr + 1.3566)*zsqrt          &
              &          + (0.37335*ztr - 0.05778)*zsal

              zck3p    = -3070.75*ztr - 18.126                    &
              &          + (17.27039*ztr + 2.81197) * zsqrt       &
              &          + (-44.99486*ztr - 0.09984) * zsal 

              ! CONSTANT FOR SILICATE, MILLERO (1995)
              zcksi    = -8904.2*ztr  + 117.400 - 19.334*zlogt   &
              &          + (-458.79*ztr + 3.5913) * zisqrt       &
              &          + (188.74*ztr - 1.5998) * zis           &
              &          + (-12.1652*ztr + 0.07871) * zis2       &
              &          + LOG(1.0 - 0.001005*zsal)

               ! APPARENT SOLUBILITY PRODUCT K'SP OF CALCITE IN SEAWATER
               !       (S=27-43, T=2-25 DEG C) at pres =0 (atmos. pressure) (MUCCI 1983)
               zaksp0  = -171.9065 -0.077993*ztkel + 2839.319*ztr + 71.595*LOG10( ztkel )   &
                  &      + (-0.77712 + 0.00284263*ztkel + 178.34*ztr) * zsqrt  &
                  &      - 0.07711*zsal + 0.0041249*zsal15

               ! CONVERT FROM DIFFERENT PH SCALES
               total2free  = 1.0/(1.0 + zst/zcks)
               free2SWS    = 1. + zst/zcks + zft/(zckf*total2free)
               total2SWS   = total2free * free2SWS
               SWS2total   = 1.0 / total2SWS

               ! K1, K2 OF CARBONIC ACID, KB OF BORIC ACID, KW (H2O) (LIT.?)
               zak1    = 10**(zck1) * total2SWS
               zak2    = 10**(zck2) * total2SWS
               zakb    = EXP( zckb ) * total2SWS
               zakw    = EXP( zckw )
               zaksp1  = 10**(zaksp0)
               zak1p   = exp( zck1p )
               zak2p   = exp( zck2p )
               zak3p   = exp( zck3p )
               zaksi   = exp( zcksi )
               zckf    = zckf * total2SWS

               ! FORMULA FOR CPEXP AFTER EDMOND & GIESKES (1970)
               !        (REFERENCE TO CULBERSON & PYTKOQICZ (1968) AS MADE
               !        IN BROECKER ET AL. (1982) IS INCORRECT; HERE RGAS IS
               !        TAKEN TENFOLD TO CORRECT FOR THE NOTATION OF pres  IN
               !        DBAR INSTEAD OF BAR AND THE EXPRESSION FOR CPEXP IS
               !        MULTIPLIED BY LN(10.) TO ALLOW USE OF EXP-FUNCTION
               !        WITH BASIS E IN THE FORMULA FOR AKSPP (CF. EDMOND
               !        & GIESKES (1970), P. 1285-1286 (THE SMALL
               !        FORMULA ON P. 1286 IS RIGHT AND CONSISTENT WITH THE
               !        SIGN IN PARTIAL MOLAR VOLUME CHANGE AS SHOWN ON P. 1285))
               zcpexp  = zpres / (rgas*ztkel)
               zcpexp2 = zpres * zcpexp

               ! KB OF BORIC ACID, K1,K2 OF CARBONIC ACID PRESSURE
               !        CORRECTION AFTER CULBERSON AND PYTKOWICZ (1968)
               !        (CF. BROECKER ET AL., 1982)

               zbuf1  = -     ( devk10 + devk20 * ztc + devk30 * ztc * ztc )
               zbuf2  = 0.5 * ( devk40 + devk50 * ztc )
               ak13(ji,jj,jk) = zak1 * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               zbuf1  =     - ( devk11 + devk21 * ztc + devk31 * ztc * ztc )
               zbuf2  = 0.5 * ( devk41 + devk51 * ztc )
               ak23(ji,jj,jk) = zak2 * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               zbuf1  =     - ( devk12 + devk22 * ztc + devk32 * ztc * ztc )
               zbuf2  = 0.5 * ( devk42 + devk52 * ztc )
               akb3(ji,jj,jk) = zakb * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               zbuf1  =     - ( devk13 + devk23 * ztc + devk33 * ztc * ztc )
               zbuf2  = 0.5 * ( devk43 + devk53 * ztc )
               akw3(ji,jj,jk) = zakw * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               zbuf1  =     - ( devk14 + devk24 * ztc + devk34 * ztc * ztc )
               zbuf2  = 0.5 * ( devk44 + devk54 * ztc )
               aks3(ji,jj,jk) = zcks * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               zbuf1  =     - ( devk15 + devk25 * ztc + devk35 * ztc * ztc )
               zbuf2  = 0.5 * ( devk45 + devk55 * ztc )
               akf3(ji,jj,jk) = zckf * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               zbuf1  =     - ( devk17 + devk27 * ztc + devk37 * ztc * ztc )
               zbuf2  = 0.5 * ( devk47 + devk57 * ztc )
               ak1p3(ji,jj,jk) = zak1p * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               zbuf1  =     - ( devk18 + devk28 * ztc + devk38 * ztc * ztc )
               zbuf2  = 0.5 * ( devk48 + devk58 * ztc )
               ak2p3(ji,jj,jk) = zak2p * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               zbuf1  =     - ( devk19 + devk29 * ztc + devk39 * ztc * ztc )
               zbuf2  = 0.5 * ( devk49 + devk59 * ztc )
               ak3p3(ji,jj,jk) = zak3p * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               zbuf1  =     - ( devk110 + devk210 * ztc + devk310 * ztc * ztc )
               zbuf2  = 0.5 * ( devk410 + devk510 * ztc )
               aksi3(ji,jj,jk) = zaksi * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               ! CONVERT FROM DIFFERENT PH SCALES
               total2free  = 1.0/(1.0 + zst/aks3(ji,jj,jk))
               free2SWS    = 1. + zst/aks3(ji,jj,jk) + zft/akf3(ji,jj,jk)
               total2SWS   = total2free * free2SWS
               SWS2total   = 1.0 / total2SWS

               ! Convert to total scale
               ak13(ji,jj,jk)  = ak13(ji,jj,jk)  * SWS2total
               ak23(ji,jj,jk)  = ak23(ji,jj,jk)  * SWS2total
               akb3(ji,jj,jk)  = akb3(ji,jj,jk)  * SWS2total
               akw3(ji,jj,jk)  = akw3(ji,jj,jk)  * SWS2total
               ak1p3(ji,jj,jk) = ak1p3(ji,jj,jk) * SWS2total
               ak2p3(ji,jj,jk) = ak2p3(ji,jj,jk) * SWS2total
               ak3p3(ji,jj,jk) = ak3p3(ji,jj,jk) * SWS2total
               aksi3(ji,jj,jk) = aksi3(ji,jj,jk) * SWS2total
               akf3(ji,jj,jk)  = akf3(ji,jj,jk)  / total2free

               ! APPARENT SOLUBILITY PRODUCT K'SP OF CALCITE 
               !        AS FUNCTION OF PRESSURE FOLLOWING MILLERO
               !        (P. 1285) AND BERNER (1976)
               zbuf1  =     - ( devk16 + devk26 * ztc + devk36 * ztc * ztc )
               zbuf2  = 0.5 * ( devk46 + devk56 * ztc )
               aksp(ji,jj,jk) = zaksp1 * EXP( zbuf1 * zcpexp + zbuf2 * zcpexp2 )

               ! TOTAL F, S, and BORATE CONCENTR. [MOLES/L]
               borat(ji,jj,jk) = 0.0002414 * zcl / 10.811
               sulfat(ji,jj,jk) = zst
               fluorid(ji,jj,jk) = zft 

               ! Iron and SIO3 saturation concentration from ...
               sio3eq(ji,jj,jk) = EXP(  LOG( 10.) * ( 6.44 - 968. / ztkel )  ) * 1.e-6
               fekeq (ji,jj,jk) = 10**( 17.27 - 1565.7 / ztkel )

               ! Liu and Millero (1999) only valid 5 - 50 degC
               ztkel1 = MAX( 5. , tempis(ji,jj,jk) ) + 273.16
               fesol(ji,jj,jk,1) = 10**((-13.486) - (0.1856* (zis**0.5)) + (0.3073*zis) + (5254.0/ztkel1))
               fesol(ji,jj,jk,2) = 10**(2.517 - (0.885*(zis**0.5)) + (0.2139 * zis) - (1320.0/ztkel1) )
               fesol(ji,jj,jk,3) = 10**(0.4511 - (0.3305*(zis**0.5)) - (1996.0/ztkel1) )
               fesol(ji,jj,jk,4) = 10**(-0.2965 - (0.7881*(zis**0.5)) - (4086.0/ztkel1) )
               fesol(ji,jj,jk,5) = 10**(4.4466 - (0.8505*(zis**0.5)) - (7980.0/ztkel1) )
            END DO
         END DO
      END DO
      !
      IF( nn_timing == 1 )  CALL timing_stop('p4z_che')
      !
   END SUBROUTINE p4z_che

   SUBROUTINE p4z_che_ahini( p_hini )
      !!---------------------------------------------------------------------
      !!                     ***  ROUTINE ahini_for_at  ***
      !!
      !! Subroutine returns the root for the 2nd order approximation of the
      !! DIC -- B_T -- A_CB equation for [H+] (reformulated as a cubic 
      !! polynomial) around the local minimum, if it exists.
      !! Returns * 1E-03_wp if p_alkcb <= 0
      !!         * 1E-10_wp if p_alkcb >= 2*p_dictot + p_bortot
      !!         * 1E-07_wp if 0 < p_alkcb < 2*p_dictot + p_bortot
      !!                    and the 2nd order approximation does not have 
      !!                    a solution
      !!---------------------------------------------------------------------
      REAL(wp), DIMENSION(jpi,jpj,jpk), INTENT(OUT)  ::  p_hini
      INTEGER  ::   ji, jj, jk
      REAL(wp)  ::  zca1, zba1
      REAL(wp)  ::  zd, zsqrtd, zhmin
      REAL(wp)  ::  za2, za1, za0
      REAL(wp)  ::  p_dictot, p_bortot, p_alkcb 

      IF( nn_timing == 1 )  CALL timing_start('p4z_che_ahini')
      !
      DO jk = 1, jpk
        DO jj = 1, jpj
          DO ji = 1, jpi
            p_alkcb  = trb(ji,jj,jk,jptal) * 1000. / (rhop(ji,jj,jk) + rtrn)
            p_dictot = trb(ji,jj,jk,jpdic) * 1000. / (rhop(ji,jj,jk) + rtrn)
            p_bortot = borat(ji,jj,jk)
            IF (p_alkcb <= 0.) THEN
                p_hini(ji,jj,jk) = 1.e-3
            ELSEIF (p_alkcb >= (2.*p_dictot + p_bortot)) THEN
                p_hini(ji,jj,jk) = 1.e-10_wp
            ELSE
                zca1 = p_dictot/( p_alkcb + rtrn )
                zba1 = p_bortot/ (p_alkcb + rtrn )
           ! Coefficients of the cubic polynomial
                za2 = aKb3(ji,jj,jk)*(1. - zba1) + ak13(ji,jj,jk)*(1.-zca1)
                za1 = ak13(ji,jj,jk)*akb3(ji,jj,jk)*(1. - zba1 - zca1)    &
                &     + ak13(ji,jj,jk)*ak23(ji,jj,jk)*(1. - (zca1+zca1))
                za0 = ak13(ji,jj,jk)*ak23(ji,jj,jk)*akb3(ji,jj,jk)*(1. - zba1 - (zca1+zca1))
                                        ! Taylor expansion around the minimum
                zd = za2*za2 - 3.*za1   ! Discriminant of the quadratic equation
                                        ! for the minimum close to the root

                IF(zd > 0.) THEN        ! If the discriminant is positive
                  zsqrtd = SQRT(zd)
                  IF(za2 < 0) THEN
                    zhmin = (-za2 + zsqrtd)/3.
                  ELSE
                    zhmin = -za1/(za2 + zsqrtd)
                  ENDIF
                  p_hini(ji,jj,jk) = zhmin + SQRT(-(za0 + zhmin*(za1 + zhmin*(za2 + zhmin)))/zsqrtd)
                ELSE
                  p_hini(ji,jj,jk) = 1.e-7
                ENDIF
             !
             ENDIF
          END DO
        END DO
      END DO
      !
      IF( nn_timing == 1 )  CALL timing_stop('p4z_che_ahini')
      !
   END SUBROUTINE p4z_che_ahini

   !===============================================================================
   SUBROUTINE anw_infsup( p_alknw_inf, p_alknw_sup )

   ! Subroutine returns the lower and upper bounds of "non-water-selfionization"
   ! contributions to total alkalinity (the infimum and the supremum), i.e
   ! inf(TA - [OH-] + [H+]) and sup(TA - [OH-] + [H+])

   ! Argument variables
   REAL(wp), DIMENSION(jpi,jpj,jpk), INTENT(OUT) :: p_alknw_inf
   REAL(wp), DIMENSION(jpi,jpj,jpk), INTENT(OUT) :: p_alknw_sup

   p_alknw_inf(:,:,:) =  -trb(:,:,:,jppo4) * 1000. / (rhop(:,:,:) + rtrn) - sulfat(:,:,:)  &
   &              - fluorid(:,:,:)
   p_alknw_sup(:,:,:) =   (2. * trb(:,:,:,jpdic) + 2. * trb(:,:,:,jppo4) + trb(:,:,:,jpsil) )    &
   &               * 1000. / (rhop(:,:,:) + rtrn) + borat(:,:,:) 

   END SUBROUTINE anw_infsup


   SUBROUTINE p4z_che_solve_hi( p_hini, zhi )

   ! Universal pH solver that converges from any given initial value,
   ! determines upper an lower bounds for the solution if required

   ! Argument variables
   !--------------------
   REAL(wp), DIMENSION(jpi,jpj,jpk), INTENT(IN)   :: p_hini
   REAL(wp), DIMENSION(jpi,jpj,jpk), INTENT(OUT)  :: zhi

   ! Local variables
   !-----------------
   INTEGER   ::  ji, jj, jk, jn
   REAL(wp)  ::  zh_ini, zh, zh_prev, zh_lnfactor
   REAL(wp)  ::  zdelta, zh_delta
   REAL(wp)  ::  zeqn, zdeqndh, zalka
   REAL(wp)  ::  aphscale
   REAL(wp)  ::  znumer_dic, zdnumer_dic, zdenom_dic, zalk_dic, zdalk_dic
   REAL(wp)  ::  znumer_bor, zdnumer_bor, zdenom_bor, zalk_bor, zdalk_bor
   REAL(wp)  ::  znumer_po4, zdnumer_po4, zdenom_po4, zalk_po4, zdalk_po4
   REAL(wp)  ::  znumer_sil, zdnumer_sil, zdenom_sil, zalk_sil, zdalk_sil
   REAL(wp)  ::  znumer_so4, zdnumer_so4, zdenom_so4, zalk_so4, zdalk_so4
   REAL(wp)  ::  znumer_flu, zdnumer_flu, zdenom_flu, zalk_flu, zdalk_flu
   REAL(wp)  ::  zalk_wat, zdalk_wat
   REAL(wp)  ::  zfact, p_alktot, zdic, zbot, zpt, zst, zft, zsit
   LOGICAL   ::  l_exitnow
   REAL(wp), PARAMETER :: pz_exp_threshold = 1.0
   REAL(wp), POINTER, DIMENSION(:,:,:) :: zalknw_inf, zalknw_sup, rmask, zh_min, zh_max, zeqn_absmin

   IF( nn_timing == 1 )  CALL timing_start('p4z_che_solve_hi')
      !  Allocate temporary workspace
   CALL wrk_alloc( jpi, jpj, jpk, zalknw_inf, zalknw_sup, rmask )
   CALL wrk_alloc( jpi, jpj, jpk, zh_min, zh_max, zeqn_absmin )

   CALL anw_infsup( zalknw_inf, zalknw_sup )

   rmask(:,:,:) = tmask(:,:,:)
   zhi(:,:,:)   = 0.

   ! TOTAL H+ scale: conversion factor for Htot = aphscale * Hfree
   DO jk = 1, jpk
      DO jj = 1, jpj
         DO ji = 1, jpi
            IF (rmask(ji,jj,jk) == 1.) THEN
               p_alktot = trb(ji,jj,jk,jptal) * 1000. / (rhop(ji,jj,jk) + rtrn)
               aphscale = 1. + sulfat(ji,jj,jk)/aks3(ji,jj,jk)
               zh_ini = p_hini(ji,jj,jk)

               zdelta = (p_alktot-zalknw_inf(ji,jj,jk))**2 + 4.*akw3(ji,jj,jk)/aphscale

               IF(p_alktot >= zalknw_inf(ji,jj,jk)) THEN
                 zh_min(ji,jj,jk) = 2.*akw3(ji,jj,jk) /( p_alktot-zalknw_inf(ji,jj,jk) + SQRT(zdelta) )
               ELSE
                 zh_min(ji,jj,jk) = aphscale*(-(p_alktot-zalknw_inf(ji,jj,jk)) + SQRT(zdelta) ) / 2.
               ENDIF

               zdelta = (p_alktot-zalknw_sup(ji,jj,jk))**2 + 4.*akw3(ji,jj,jk)/aphscale

               IF(p_alktot <= zalknw_sup(ji,jj,jk)) THEN
                 zh_max(ji,jj,jk) = aphscale*(-(p_alktot-zalknw_sup(ji,jj,jk)) + SQRT(zdelta) ) / 2.
               ELSE
                 zh_max(ji,jj,jk) = 2.*akw3(ji,jj,jk) /( p_alktot-zalknw_sup(ji,jj,jk) + SQRT(zdelta) )
               ENDIF

               zhi(ji,jj,jk) = MAX(MIN(zh_max(ji,jj,jk), zh_ini), zh_min(ji,jj,jk))
            ENDIF
         END DO
      END DO
   END DO

   zeqn_absmin(:,:,:) = HUGE(1._wp)

   DO jn = 1, jp_maxniter_atgen 
   DO jk = 1, jpk
      DO jj = 1, jpj
         DO ji = 1, jpi
            IF (rmask(ji,jj,jk) == 1.) THEN
               zfact = rhop(ji,jj,jk) / 1000. + rtrn
               p_alktot = trb(ji,jj,jk,jptal) / zfact
               zdic  = trb(ji,jj,jk,jpdic) / zfact
               zbot  = borat(ji,jj,jk)
               zpt = trb(ji,jj,jk,jppo4) / zfact * po4r
               zsit = trb(ji,jj,jk,jpsil) / zfact
               zst = sulfat (ji,jj,jk)
               zft = fluorid(ji,jj,jk)
               aphscale = 1. + sulfat(ji,jj,jk)/aks3(ji,jj,jk)
               zh = zhi(ji,jj,jk)
               zh_prev = zh

               ! H2CO3 - HCO3 - CO3 : n=2, m=0
               znumer_dic = 2.*ak13(ji,jj,jk)*ak23(ji,jj,jk) + zh*ak13(ji,jj,jk)
               zdenom_dic = ak13(ji,jj,jk)*ak23(ji,jj,jk) + zh*(ak13(ji,jj,jk) + zh)
               zalk_dic   = zdic * (znumer_dic/zdenom_dic)
               zdnumer_dic = ak13(ji,jj,jk)*ak13(ji,jj,jk)*ak23(ji,jj,jk) + zh     &
                             *(4.*ak13(ji,jj,jk)*ak23(ji,jj,jk) + zh*ak13(ji,jj,jk))
               zdalk_dic   = -zdic*(zdnumer_dic/zdenom_dic**2)


               ! B(OH)3 - B(OH)4 : n=1, m=0
               znumer_bor = akb3(ji,jj,jk)
               zdenom_bor = akb3(ji,jj,jk) + zh
               zalk_bor   = zbot * (znumer_bor/zdenom_bor)
               zdnumer_bor = akb3(ji,jj,jk)
               zdalk_bor   = -zbot*(zdnumer_bor/zdenom_bor**2)


               ! H3PO4 - H2PO4 - HPO4 - PO4 : n=3, m=1
               znumer_po4 = 3.*ak1p3(ji,jj,jk)*ak2p3(ji,jj,jk)*ak3p3(ji,jj,jk)  &
               &            + zh*(2.*ak1p3(ji,jj,jk)*ak2p3(ji,jj,jk) + zh* ak1p3(ji,jj,jk))
               zdenom_po4 = ak1p3(ji,jj,jk)*ak2p3(ji,jj,jk)*ak3p3(ji,jj,jk)     &
               &            + zh*( ak1p3(ji,jj,jk)*ak2p3(ji,jj,jk) + zh*(ak1p3(ji,jj,jk) + zh))
               zalk_po4   = zpt * (znumer_po4/zdenom_po4 - 1.) ! Zero level of H3PO4 = 1
               zdnumer_po4 = ak1p3(ji,jj,jk)*ak2p3(ji,jj,jk)*ak1p3(ji,jj,jk)*ak2p3(ji,jj,jk)*ak3p3(ji,jj,jk)  &
               &             + zh*(4.*ak1p3(ji,jj,jk)*ak1p3(ji,jj,jk)*ak2p3(ji,jj,jk)*ak3p3(ji,jj,jk)         &
               &             + zh*(9.*ak1p3(ji,jj,jk)*ak2p3(ji,jj,jk)*ak3p3(ji,jj,jk)                         &
               &             + ak1p3(ji,jj,jk)*ak1p3(ji,jj,jk)*ak2p3(ji,jj,jk)                                &
               &             + zh*(4.*ak1p3(ji,jj,jk)*ak2p3(ji,jj,jk) + zh * ak1p3(ji,jj,jk) ) ) )
               zdalk_po4   = -zpt * (zdnumer_po4/zdenom_po4**2)

               ! H4SiO4 - H3SiO4 : n=1, m=0
               znumer_sil = aksi3(ji,jj,jk)
               zdenom_sil = aksi3(ji,jj,jk) + zh
               zalk_sil   = zsit * (znumer_sil/zdenom_sil)
               zdnumer_sil = aksi3(ji,jj,jk)
               zdalk_sil   = -zsit * (zdnumer_sil/zdenom_sil**2)

               ! HSO4 - SO4 : n=1, m=1
               aphscale = 1.0 + zst/aks3(ji,jj,jk)
               znumer_so4 = aks3(ji,jj,jk) * aphscale
               zdenom_so4 = aks3(ji,jj,jk) * aphscale + zh
               zalk_so4   = zst * (znumer_so4/zdenom_so4 - 1.)
               zdnumer_so4 = aks3(ji,jj,jk)
               zdalk_so4   = -zst * (zdnumer_so4/zdenom_so4**2)

               ! HF - F : n=1, m=1
               znumer_flu =  akf3(ji,jj,jk)
               zdenom_flu =  akf3(ji,jj,jk) + zh
               zalk_flu   =  zft * (znumer_flu/zdenom_flu - 1.)
               zdnumer_flu = akf3(ji,jj,jk)
               zdalk_flu   = -zft * (zdnumer_flu/zdenom_flu**2)

               ! H2O - OH
               aphscale = 1.0 + zst/aks3(ji,jj,jk)
               zalk_wat   = akw3(ji,jj,jk)/zh - zh/aphscale
               zdalk_wat  = -akw3(ji,jj,jk)/zh**2 - 1./aphscale

               ! CALCULATE [ALK]([CO3--], [HCO3-])
               zeqn = zalk_dic + zalk_bor + zalk_po4 + zalk_sil   &
               &      + zalk_so4 + zalk_flu                       &
               &      + zalk_wat - p_alktot

               zalka = p_alktot - (zalk_bor + zalk_po4 + zalk_sil   &
               &       + zalk_so4 + zalk_flu + zalk_wat)

               zdeqndh = zdalk_dic + zdalk_bor + zdalk_po4 + zdalk_sil &
               &         + zdalk_so4 + zdalk_flu + zdalk_wat

               ! Adapt bracketing interval
               IF(zeqn > 0._wp) THEN
                 zh_min(ji,jj,jk) = zh_prev
               ELSEIF(zeqn < 0._wp) THEN
                 zh_max(ji,jj,jk) = zh_prev
               ENDIF

               IF(ABS(zeqn) >= 0.5_wp*zeqn_absmin(ji,jj,jk)) THEN
               ! if the function evaluation at the current point is
               ! not decreasing faster than with a bisection step (at least linearly)
               ! in absolute value take one bisection step on [ph_min, ph_max]
               ! ph_new = (ph_min + ph_max)/2d0
               !
               ! In terms of [H]_new:
               ! [H]_new = 10**(-ph_new)
               !         = 10**(-(ph_min + ph_max)/2d0)
               !         = SQRT(10**(-(ph_min + phmax)))
               !         = SQRT(zh_max * zh_min)
                  zh = SQRT(zh_max(ji,jj,jk) * zh_min(ji,jj,jk))
                  zh_lnfactor = (zh - zh_prev)/zh_prev ! Required to test convergence below
               ELSE
               ! dzeqn/dpH = dzeqn/d[H] * d[H]/dpH
               !           = -zdeqndh * LOG(10) * [H]
               ! \Delta pH = -zeqn/(zdeqndh*d[H]/dpH) = zeqn/(zdeqndh*[H]*LOG(10))
               !
               ! pH_new = pH_old + \deltapH
               !
               ! [H]_new = 10**(-pH_new)
               !         = 10**(-pH_old - \Delta pH)
               !         = [H]_old * 10**(-zeqn/(zdeqndh*[H]_old*LOG(10)))
               !         = [H]_old * EXP(-LOG(10)*zeqn/(zdeqndh*[H]_old*LOG(10)))
               !         = [H]_old * EXP(-zeqn/(zdeqndh*[H]_old))

                  zh_lnfactor = -zeqn/(zdeqndh*zh_prev)

                  IF(ABS(zh_lnfactor) > pz_exp_threshold) THEN
                     zh          = zh_prev*EXP(zh_lnfactor)
                  ELSE
                     zh_delta    = zh_lnfactor*zh_prev
                     zh          = zh_prev + zh_delta
                  ENDIF

                  IF( zh < zh_min(ji,jj,jk) ) THEN
                     ! if [H]_new < [H]_min
                     ! i.e., if ph_new > ph_max then
                     ! take one bisection step on [ph_prev, ph_max]
                     ! ph_new = (ph_prev + ph_max)/2d0
                     ! In terms of [H]_new:
                     ! [H]_new = 10**(-ph_new)
                     !         = 10**(-(ph_prev + ph_max)/2d0)
                     !         = SQRT(10**(-(ph_prev + phmax)))
                     !         = SQRT([H]_old*10**(-ph_max))
                     !         = SQRT([H]_old * zh_min)
                     zh                = SQRT(zh_prev * zh_min(ji,jj,jk))
                     zh_lnfactor       = (zh - zh_prev)/zh_prev ! Required to test convergence below
                  ENDIF

                  IF( zh > zh_max(ji,jj,jk) ) THEN
                     ! if [H]_new > [H]_max
                     ! i.e., if ph_new < ph_min, then
                     ! take one bisection step on [ph_min, ph_prev]
                     ! ph_new = (ph_prev + ph_min)/2d0
                     ! In terms of [H]_new:
                     ! [H]_new = 10**(-ph_new)
                     !         = 10**(-(ph_prev + ph_min)/2d0)
                     !         = SQRT(10**(-(ph_prev + ph_min)))
                     !         = SQRT([H]_old*10**(-ph_min))
                     !         = SQRT([H]_old * zhmax)
                     zh                = SQRT(zh_prev * zh_max(ji,jj,jk))
                     zh_lnfactor       = (zh - zh_prev)/zh_prev ! Required to test convergence below
                  ENDIF
               ENDIF

               zeqn_absmin(ji,jj,jk) = MIN( ABS(zeqn), zeqn_absmin(ji,jj,jk))

               ! Stop iterations once |\delta{[H]}/[H]| < rdel
               ! <=> |(zh - zh_prev)/zh_prev| = |EXP(-zeqn/(zdeqndh*zh_prev)) -1| < rdel
               ! |EXP(-zeqn/(zdeqndh*zh_prev)) -1| ~ |zeqn/(zdeqndh*zh_prev)|

               ! Alternatively:
               ! |\Delta pH| = |zeqn/(zdeqndh*zh_prev*LOG(10))|
               !             ~ 1/LOG(10) * |\Delta [H]|/[H]
               !             < 1/LOG(10) * rdel

               ! Hence |zeqn/(zdeqndh*zh)| < rdel

               ! rdel <-- pp_rdel_ah_target
               l_exitnow = (ABS(zh_lnfactor) < pp_rdel_ah_target)

               IF(l_exitnow) THEN 
                  rmask(ji,jj,jk) = 0.
               ENDIF

               zhi(ji,jj,jk) =  zh

               IF(jn >= jp_maxniter_atgen) THEN
                  zhi(ji,jj,jk) = -1._wp
               ENDIF

            ENDIF
         END DO
      END DO
   END DO
   END DO
   !
   CALL wrk_dealloc( jpi, jpj, jpk, zalknw_inf, zalknw_sup, rmask )
   CALL wrk_dealloc( jpi, jpj, jpk, zh_min, zh_max, zeqn_absmin )


   IF( nn_timing == 1 )  CALL timing_stop('p4z_che_solve_hi')


   END SUBROUTINE p4z_che_solve_hi

   INTEGER FUNCTION p4z_che_alloc()
      !!----------------------------------------------------------------------
      !!                     ***  ROUTINE p4z_che_alloc  ***
      !!----------------------------------------------------------------------
      INTEGER ::   ierr(3)        ! Local variables
      !!----------------------------------------------------------------------

      ierr(:) = 0

      ALLOCATE( sio3eq(jpi,jpj,jpk), fekeq(jpi,jpj,jpk), chemc(jpi,jpj,3), chemo2(jpi,jpj,jpk), STAT=ierr(1) )

      ALLOCATE( akb3(jpi,jpj,jpk)     , tempis(jpi, jpj, jpk),       &
         &      akw3(jpi,jpj,jpk)     , borat (jpi,jpj,jpk)  ,       &
         &      aks3(jpi,jpj,jpk)     , akf3(jpi,jpj,jpk)    ,       &
         &      ak1p3(jpi,jpj,jpk)    , ak2p3(jpi,jpj,jpk)   ,       &
         &      ak3p3(jpi,jpj,jpk)    , aksi3(jpi,jpj,jpk)   ,       &
         &      fluorid(jpi,jpj,jpk)  , sulfat(jpi,jpj,jpk)  ,       &
         &      salinprac(jpi,jpj,jpk),                 STAT=ierr(2) )

      ALLOCATE( fesol(jpi,jpj,jpk,5), STAT=ierr(3) )

      !* Variable for chemistry of the CO2 cycle
      p4z_che_alloc = MAXVAL( ierr )
      !
      IF( p4z_che_alloc /= 0 )   CALL ctl_warn('p4z_che_alloc : failed to allocate arrays.')
      !
   END FUNCTION p4z_che_alloc

#else
   !!======================================================================
   !!  Dummy module :                                   No PISCES bio-model
   !!======================================================================
CONTAINS
   SUBROUTINE p4z_che( kt )                   ! Empty routine
      INTEGER, INTENT(in) ::   kt
      WRITE(*,*) 'p4z_che: You should not have seen this print! error?', kt
   END SUBROUTINE p4z_che
#endif 

   !!======================================================================
END MODULE  p4zche